THERMAL-CRACKING OF SUBSTITUTED AROMATIC-HYDROCARBONS .2. KINETIC-STUDY OF THE THERMAL-CRACKING OF NORMAL-PROPYLBENZENE AND ETHYLBENZENE

被引：23

作者：

CHEN, Q ^{[1
]}

FROMENT, GF ^{[1
]}

机构：

[1] STATE UNIV GHENT,PETROCHEM TECH LAB,B-9000 GHENT,BELGIUM

来源：

JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS | 1991年 / 21卷 / 1-2期

关键词：

AROMATIC HYDROCARBONS; ETHYLBENZENE; KINETIC MODELS; NORMAL-PROPYLBENZENE; PYROLYSIS; THERMAL CRACKING;

D O I：

10.1016/0165-2370(91)80015-Z

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A complete free radical reaction network was established for the thermal cracking of n-propylbenzene on the basis of the cumene cracking model and experiments on n-propylbenzene cracking. The parameters for the reactions common to the cumene model and the n-propylbenzene model were taken from the cumene cracking model. The cracking reactions of cumene and n-propylbenzene were compared. The model of n-propylbenzene cracking was tested with the ethylbenzene cracking. This provides strong support for the adequacy of the n-propylbenzene and cumene cracking models.

引用

页码：51 / 77

页数：27

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