SYNTHESIS OF L-ORNITHINES STEREOSPECIFICALLY DEUTERATED AT C-3

被引：13

作者：

BALDWIN, JE ^{[1
]}

MERRITT, KD ^{[1
]}

SCHOFIELD, CJ ^{[1
]}

机构：

[1] OXFORD CTR MOLEC SCI,OXFORD OX1 3QY,ENGLAND

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 24期

关键词：

D O I：

10.1016/S0040-4039(00)79263-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(2S, 3S)-[2,3-H-2(2)]-Ornithine and (2S, 3R)-[3-H-2(1)]-ornithine were prepared with high stereoselectivity via asymmetric reduction catalysed by {bicyclo[2.2.1]hepta-2,5-diene}{(R)-1,2-bis(diphenylphosphino)propane}rhodium (1) trifluoromethanesulphonate [(R)-Rh-Prophos].

引用

收藏

页码：3919 / 3920

页数：2

相关论文

共 13 条

[1]

BALDWIN JE, UNPUB J CHEM SOC CHE

[2] NATURALLY-OCCURRING BETA-LACTAMASE INHIBITORS WITH ANTIBACTERIAL ACTIVITY [J].

BROWN, AG ;

BUTTERWORTH, D ;

COLE, M ;

HANSCOMB, G ;

HOOD, JD ;

READING, C .

JOURNAL OF ANTIBIOTICS, 1976, 29 (06) :668-669

[3] ASYMMETRIC CATALYSIS WITH CHIRAL COMPLEXES OF RHODIUM-O-ISOPROPYLIDENE-2,3-DIHYDROXY-1,4-BIS(DIPHENYLPHOSPHINO)-BUTANE .6. MECHANISM OF REDUCTION OF (E,Z)-ALPHA-ACYLAMINOCINNAMIC ACIDS WITH HOMOGENEOUS RHODIUM CATALYSTS [J].

DETELLIER, C ;

GELBARD, G ;

KAGAN, HB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (24) :7556-7561

[4] ASYMMETRIC SYNTHESIS - ASYMMETRIC HOMOGENEOUS HYDROGENATION CATALYST WHICH BREEDS ITS OWN CHIRALITY [J].

FRYZUK, MD ;

BOSNICH, B .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (17) :5491-5494

[5] TRIS[3-(TRIFLUOROMETHYLHYDROXYMETHYLENE)-D-CAMPHORATO]EUROPIUM(III) - CHIRAL SHIFT REAGENT FOR DIRECT DETERMINATION OF ENANTIOMERIC COMPOSITIONS [J].

GOERING, HL ;

EIKENBER.JN ;

KOERMER, GS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (22) :5913-&

[6]

GREENSTEIN JP, 1961, CHEM AMINO ACIDS, V3, P2479

[7] OXIDATION OF LONG-CHAIN AND RELATED ALCOHOLS TO CARBONYLS BY DIMETHYL-SULFOXIDE ACTIVATED BY OXALYL CHLORIDE [J].

MANCUSO, AJ ;

HUANG, SL ;

SWERN, D .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (12) :2480-2482

[8]

OREILLY NJ, 1990, SYNTHESIS-STUTTGART, P550

[9] BIOSYNTHESIS OF BLASTICIDIN-S FROM L-ALPHA-ARGININE - STEREOCHEMISTRY IN THE ARGININE-2,3-AMINOMUTASE REACTION [J].

PRABHAKARAN, PC ;

WOO, NT ;

YORGEY, PS ;

GOULD, SJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (17) :5785-5791

[10] SYNTHESIS OF CHIRALLY DEUTERIATED PHTHALIMIDOPROPANOLS AND EVALUATION OF THEIR ABSOLUTE STEREOCHEMISTRY [J].

PRABHAKARAN, PC ;

GOULD, SJ ;

ORR, GR ;

COWARD, JK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (17) :5779-5784