SYNTHESIS AND X-RAY STRUCTURE OF [(ETA(5)-C(5)ME(5))TI(MU(3)-O)(3)(RH(COD))(3)] (COD=CYCLOOCTA-1,5-DIENE) - ORGANOMETALLIC APPROACH TO STRONG METAL-SUPPORT INTERACTION IN HETEROGENEOUS CATALYSIS

被引：15

作者：

FANDOS, R

FIERRO, JLG

KUBICKI, MM

OTERO, A

TERREROS, P

VIVARCERRATO, MA

机构：

[1] UNIV CASTILLA LA MANCHA, FAC QUIM, DEPT QUIM INORGAN ORGAN & BIOQUIM, E-13071 CIUDAD REAL, SPAIN

[2] CSIC, INST CATALISIS & PETROLEOQUIM, E-28049 MADRID, SPAIN

[3] FAC SCI DIJON, CNRS, URA 1685, SYNTH & ELECTROSYNTH ORGANOMET LAB, F-21000 DIJON, FRANCE

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 05期

关键词：

D O I：

10.1021/om00005a013

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[(eta(5)-C(5)Me(5))TiMe(3)] (1) reacts with [Rh(mu(2)-OH)(COD)](2) (2) to yield [(eta(5)-C(5)Me(5))Ti(mu(3)-O)(3){Rh(COD)}(3)] (3). The molecular structure of 3 shows that it can be compared to the cubane type structures M(4)X(4) in which the fourth X ligand position is absent.

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页码：2162 / 2163

页数：2

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