KINETICS OF CERIUM (4) OXIDATION OF BENZALDEHYDE

被引：43

作者：

WIBERG, KB

FORD, PC

机构：

[1] Department of Chemistry, Yale University, New Haven

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 01期

关键词：

D O I：

10.1021/ja01029a026

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The kinetics of the cerium(IV) oxidation of benzaldehyde to benzoic acid were studied in 85 % aqueous acetic acid. The first reaction was the formation of a 1:1 benzaldehyde-ceric ion complex. This was followed by an acid-catalyzed decomposition of the complex as well as of a 2:1 benzaldehyde-ceric ion complex which is present in relatively low concentration. Evidence was found for the formation of benzoyl radicals as an intermediate, and the reaction was found to give a kinetic isotope effect. © 1969, American Chemical Society. All rights reserved.

引用

页码：124 / &

共 10 条

[1]

BRUCKENSTEIN S, 1952, THESIS U MINNESOTA

[2] KINETICS OF THALLIUM(I)-CERIUM(IV) REACTION IN NITRIC ACID [J].