CARBON-DIOXIDE AS MODULATOR OF THE OXIDATIVE PROPERTIES OF DIOXYGEN IN THE PRESENCE OF TRANSITION-METAL SYSTEMS

被引：53

作者：

ARESTA, M ^{[1
]}

FRAGALE, C ^{[1
]}

QUARANTA, E ^{[1
]}

TOMMASI, I ^{[1
]}

机构：

[1] UNIV BARI,CTR CNR,MISO,I-70126 BARI,ITALY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 04期

关键词：

D O I：

10.1039/c39920000315

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the presence of transition metal (Fe, Rh) catalysts, CO2 can modulate the oxidative properties of O2 towards tetrahydrofuran (THF) and styrene; the intermediate formation of metal-peroxocarbonate species, [L(n) activated MOC(O)O-O], seems to play a key role in these processes.

引用

页码：315 / 317

页数：3

共 17 条

[1] INTERACTION OF CARBON-DIOXIDE WITH COORDINATIVELY UNSATURATED RHODIUM(I) COMPLEXES WITH THE LIGAND 1,2-BIS(DIPHENYLPHOSPHINO)ETHANE
ALBANO, P
ARESTA, M
MANASSERO, M
[J]. INORGANIC CHEMISTRY, 1980, 19 (04) : 1069 - 1072
[2] IRON(O) OXIDATION BY HYDROGEN-CHLORIDE IN TETRAHYDROFURAN - SIMPLE WAY TO ANHYDROUS IRON(II) CHLORIDE
ARESTA, M
NOBILE, CF
PETRUZZELLI, D
[J]. INORGANIC CHEMISTRY, 1977, 16 (07) : 1817 - 1818
[3] (CARBON DIOXIDE)BIS(TRIALKYLPHOSPHINE)NICKEL COMPLEXES
ARESTA, M
NOBILE, CF
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (07): : 708 - 711
[4] DIRECT SYNTHESIS OF 1,3-BENZODIOXOL-2-ONE FROM STYRENE, DIOXYGEN AND CARBON-DIOXIDE PROMOTED BY RH(I)
ARESTA, M
QUARANTA, E
CICCARESE, A
[J]. JOURNAL OF MOLECULAR CATALYSIS, 1987, 41 (03): : 355 - 359
[5] Aresta M., 1985, C1 MOL CHEM, V2, P267
[6] ARESTA M, UNPUB
[7] CLEAVAGE OF TETRAHYDROFURAN DURING REDUCTIONS WITH LITHIUM ALUMINUM HYDRIDE
BAILEY, WJ
MARKTSCHEFFEL, F
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1960, 25 (10) : 1797 - 1800
[8] SELECTIVE OXYGENATION OF ALIPHATIC ETHERS CATALYZED BY RUTHENIUM(II) COMPLEXES
BRESSAN, M
MORVILLO, A
ROMANELLO, G
[J]. INORGANIC CHEMISTRY, 1990, 29 (16) : 2976 - 2979
[9] Bruice TC, 1988, MECHANISTIC PRINCIPL, P227
[10] FREED S, 1941, J AM CHEM SOC, V63, P2691

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