METAL-COMPLEXES IN BIOLOGY AND MEDICINE .4. SYNTHESIS AND STRUCTURE OF BIS(2-AMINOETHANETHIOLATO)BISMUTH(III) NITRATE MONOHYDRATE

被引：17

作者：

HERRMANN, WA

KIPROF, P

SCHERER, W

PAJDLA, L

机构：

[1] Anorganisch-chemisches Institut, Technischen Universität München, Garching, W-8046

来源：

CHEMISCHE BERICHTE-RECUEIL | 1992年 / 125卷 / 12期

关键词：

BISMUTH COMPLEXES; 2-AMINOETHANETHIOL;

D O I：

10.1002/cber.19921251206

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of bismuth(III) nitrate with 2-aminoethanethiol results in the formation of bis(2-aminoethanethiolato)bismuth(III) nitrate monohydrate (1), the solid-state structure of which has been established by single-crystal X-ray diffraction. The bidentate chelating ligand leads to the formation of BiSCCN five-membered rings. Due to interaction of neighbouring units via Bi - S bonds, a polymeric three-dimensional structure results in the crystal lattice. The bismuth atom has an eightfold coordination with two coordination sites being provided by sulphur atoms of adjacent molecules.

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页码：2657 / 2660

页数：4

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