HIGH-RESOLUTION HE-I PHOTOELECTRON-SPECTRUM OF ACRYLONITRILE

被引：17

作者：

DELWICHE, J

GOCHELDUPUIS, M

COLLIN, JE

HEINESCH, J

机构：

[1] Laboratoire de Spectroscopie de Photoélectrons, Université de Liège, Institut de Chimie, Sart Tilman par B-4000 Liege 1

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 1993年 / 66卷 / 1-2期

关键词：

D O I：

10.1016/0368-2048(93)01829-4

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The photoelectron spectrum of acrylonitrile has been revisited under high resolution and high sensitivity using the He I resonance line. Ionisation of the outermost molecular orbitals is discussed in terms of ionisation energies and vibrational wavenumbers. Additional vibration features are reported.

引用

页码：65 / 74

页数：10

共 23 条

[1] HIGH-RESOLUTION PHOTOELECTRON-SPECTROSCOPY THROUGH DECONVOLUTION [J].

ALLEN, JD ;

GRIMM, FA .

CHEMICAL PHYSICS LETTERS, 1979, 66 (01) :72-78

[2] INTERPRETATIVE METHODS IN PHOTOELECTRON SPECTROSCOPY .2. LOW-ENERGY SPECTRA OF ORGANIC PSEUDOHALIDES AND COMPOUNDS CONTAINING HALOGEN AND PHOSPHORUS LONE PAIR ELECTRONS [J].

BAYBUTT, P ;

GUEST, MF ;

HILLIER, IH .

MOLECULAR PHYSICS, 1973, 25 (05) :1025-1036

[3] 30.4-NM HE(II) PHOTO-ELECTRON SPECTRA OF ORGANIC-MOLECULES .7. MISCELLANEOUS COMPOUNDS [J].

BIERI, G ;

ASBRINK, L ;

VONNIESSEN, W .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1982, 27 (02) :129-178

[4]

DELWICHE J, 1982, J ELECTRON SPECTROSC, V48, P123

[5]

Eland J. H. D., 1984, PHOTOELECTRON SPECTR

[6]

FUJIKAWA T, 1976, B CHEM SOC JPN, V98, P1486

[7]

GOCHELDUPUIS M, 1992, THESIS U LIEGE BELGI

[8] THE VIBRATIONAL SPECTRUM AND THERMODYNAMIC FUNCTIONS OF ACRYLONITRILE [J].

HALVERSON, F ;

STAMM, RF ;

WHALEN, JJ .

JOURNAL OF CHEMICAL PHYSICS, 1948, 16 (08) :808-816

[9] INTERACTION OF ORBITALS THROUGH SPACE AND THROUGH BONDS [J].

HOFFMANN, R .

ACCOUNTS OF CHEMICAL RESEARCH, 1971, 4 (01) :1-&

[10] IONIZATION-POTENTIALS, ELECTRON AFFINITIES, AND REACTIVITIES OF CYANOALKENES AND RELATED ELECTRON-DEFICIENT ALKENES - FRONTIER MOLECULAR-ORBITAL TREATMENT OF CYANOALKENE REACTIVITIES IN CYCLOADDITION, ELECTROPHILIC, NUCLEOPHILIC, AND RADICAL REACTIONS [J].

HOUK, KN ;

MUNCHAUSEN, LL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1976, 98 (04) :937-946

← 1 2 3 →