A SIMPLE WAY FOR THE IMPROVEMENT OF SEPARATION SELECTIVITY OF HYDROCARBONS BY O/W/O EMULSION LIQUID MEMBRANE

被引:12
作者
EGASHIRA, R [1 ]
TANNO, H [1 ]
KATO, S [1 ]
KAWASAKI, J [1 ]
机构
[1] TOKYO INST TECHNOL,DEPT CHEM ENGN,TOKYO 152,JAPAN
关键词
MEMBRANE SEPARATION; EMULSION LIQUID MEMBRANE; HYDROCARBON SEPARATION; SEPARATION SELECTIVITY IMPROVEMENT; PERMEATION MECHANISM; SUPPORTED LIQUID MEMBRANE;
D O I
10.1252/jcej.28.38
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
Transfer of hydrocarbons in an O/W emulsion drop was simulated by the dimensionless multi-layer liquid membrane model in order to find a way of improving the separation selectivity of an emulsion liquid membrane, which will be of practical use. The results suggested that the selectivity of the emulsion membrane, lowered by the unfavorable concentration profile which appeared in an emulsion drop, would be improved by decreasing the number of inner oil droplets in the emulsion drop. A series of batch permeation experiments were conducted with a one-dimensional supported liquid membrane and an emulsion liquid membrane. The separation selectivity of the supported membrane was equivalent to that of the mono-layer liquid membrane and that of the emulsion membrane was lower, Selectivity of the emulsion membrane could be improved by decreasing the number of inner droplets in the emulsion drop as suggested by the simulation, These experimental confirmations of the suggested model led to a simple way of improving the separation selectivity of this separation technique.
引用
收藏
页码:38 / 45
页数:8
相关论文
共 13 条
[1]  
CAHN RP, 1976, J MEMBRANE SCI, V1, P129
[2]   HYDROCARBON SEPARATION THROUGH A LIQUID WATER MEMBRANE - MODELING OF PERMEATION IN AN EMULSION DROP [J].
CASAMATTA, G ;
CHAVARIE, C ;
ANGELINO, H .
AICHE JOURNAL, 1978, 24 (06) :945-949
[3]  
EGASHIRA R, 1989, P INT C RECENT DEV P, P1
[4]  
EGASHIRA R, 1992, 1990 P INT C SOLV EX, P1595
[5]  
GOSWAMI AN, 1984, J CHEM TECH BIOT A, V34, P174
[6]   CONTINUOUS DEMULSIFICATION OF O/W EMULSIONS BY A MECHANICAL TECHNIQUE [J].
KATO, S ;
KAWASAKI, J .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1988, 21 (03) :321-323
[7]   A NEW TECHNIQUE FOR THE MECHANICAL DEMULSIFICATION OF O/W EMULSIONS [J].
KATO, S ;
KAWASAKI, J .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1987, 20 (03) :232-237
[8]  
KATO S, 1987, SEKIYU GAKKAISHI, V30, P1
[9]  
Kato S., 1986, SEKIYU GAKKAISHI, V29, P404
[10]   RATES OF PERMEATION AND MEMBRANE STABILITIES IN SEPARATION OF HYDROCARBONS BY LIQUID MEMBRANE [J].
KAWASAKI, J ;
SUZUKI, T ;
KATO, S ;
TOYODA, I ;
KONDO, I .
KAGAKU KOGAKU RONBUNSHU, 1987, 13 (04) :487-493