O-H AND O-D STRETCHING VIBRATIONS IN ISOTOPICALLY DILUTE HDO MOLECULES IN SOME SOLID HYDRATES

被引：128

作者：

BERGLUND, B

LINDGREN, J

TEGENFELDT, J

机构：

[1] Institute of Chemistry. University of Uppsala, Box 531

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1978年 / 43卷 / 02期

关键词：

D O I：

10.1016/0022-2860(78)80004-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Vibrational frequencies vOH and vOD have been measured for isotopically-dilute HDO molecules in eleven solid hydrates at 90 K. The results have been used to prepare a plot of the ratio vOH/vOD versus vOH. The ratios fall on a smooth curve and decrease with decreasing frequencies vOH. The anharmonicity constants ωexe have been estimated. They were found to increase with decreasing vOH. © 1978.

引用

页码：169 / 177

页数：9

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