INTRAMOLECULAR ADDITION OF CARBON-CENTERED TINTHIOIMIDOYL RADICALS TO CARBON CARBON DOUBLE-BONDS - SYNTHESIS OF GAMMA-THIOLACTAMS AND DELTA-THIOLACTAMS

被引：55

作者：

BACHI, MD

DENENMARK, D

机构：

[1] Department of Organic Chemistry, The Weizmann Institute of Science

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 11期

关键词：

D O I：

10.1021/jo00298a008

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

: (Tri-rc-butyltin)thioimidoyl radicals of type 6, which were efficiently generated by treatment of alk-3-enyl-and alk-4-enylisothiocyanates with tri-n-butyltin hydride and AIBN, underwent exo cyclization to give, after hydrolysis, the corresponding 7- or 5-thiolactams in good to excellent yields. © 1990, American Chemical Society. All rights reserved.

引用

页码：3442 / 3444

页数：3

共 30 条

[1]

BACHI MD, 1989, HETEROCYCLES, V28, P583

[2] CYCLIZATIONS OF ENE RADICALS - IMIDOYL RADICALS AS INTERMEDIATES IN THE SYNTHESIS OF HETEROCYCLIC-COMPOUNDS [J].