PREPARATION OF BETA-SILYL-ALPHA, BETA-UNSATURATED ESTERS AND 3-SILYL ALLYL ALCOHOLS

被引：15

作者：

LARSON, GL

SODERQUIST, JA

CLAUDIO, MR

机构：

[1] Department of Chemistry, University of Puerto Rico, Rio, Piedras, PR

来源：

SYNTHETIC COMMUNICATIONS | 1990年 / 20卷 / 08期

关键词：

D O I：

10.1080/00397919008052816

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Acylsilanes react with lithium α-silyl ester enolates to provide β-silyl-α, β-unsaturated esters having predominantly the (Z) geometry. These esters were reacted with Grignard reagents and with lithium aluminum hydride to give the corresponding (Z) 3-silyl allyl alcohols. Copyright © 1990 by Taylor & Francis Group. All rights reserved.

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页码：1095 / 1104

页数：10

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