SYNTHESIS OF TRANSITION-METAL PHOSPHIDES FROM THEIR OXIDES USING THE CHEMICAL-TRANSPORT (CVT) METHOD

被引：15

作者：

MARTIN, J

GRUEHN, R

机构：

[1] Institut für Anorganische, Analytische Chemie der Justus-Liebig-Universität Gießen, D-6300 Gießen

来源：

SOLID STATE IONICS | 1990年 / 43卷

关键词：

D O I：

10.1016/0167-2738(90)90465-4

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Phosphides of the composition MP (MZr, Hf, Nb, Ta, W) and M3P4 (MTh, U) have been prepared by reduction of the respective metal oxides with aluminium adding phosphorus and some iodine in an evacuated silica ampoule. Well developed crystals of the metal phosphides could be separated from the reaction mixture by subsequent chemical transport in the synthesis- ampoule. © 1990.

引用

页码：19 / 22

页数：4

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