SELECTIVE AIR OXIDATION OF LIGHT ALKANES CATALYZED BY ACTIVATED METALLOPORPHYRINS - THE SEARCH FOR A SUPRABIOTIC SYSTEM

被引：272

作者：

ELLIS, PE

LYONS, JE

机构：

[1] Sun Refining and Marketing Company Research, Development Division, Chemicals and Catalyst Technology Department, Marcus Hook, PA 19061

来源：

COORDINATION CHEMISTRY REVIEWS | 1990年 / 105卷

关键词：

D O I：

10.1016/0010-8545(90)80022-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Halogenated metalloporphyrins have been examined as catalysts for the air oxidation of propane and isobutane at low temperature. Room temperature oxidation of isobutane with air gives > 13,000 turnovers with > 90% selectivity to tert-butyl alcohol. © 1990.

引用

页码：181 / 193

页数：13

共 32 条

[1] ON PREPARATION OF METALLOPORPHYRINS [J].

ADLER, AD ;

LONGO, FR ;

KAMPAS, F ;

KIM, J .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1970, 32 (07) :2443-&

[2]

BALCH AL, 1984, J AM CHEM SOC, V106, P7779, DOI 10.1021/ja00337a022

[3]

CALLOT HJ, 1974, B SOC CHIM FR II-CH, P1492

[4] NIH SHIFT IN HAEMIN-IODOSYLBENZENE-MEDIATED HYDROXYLATIONS [J].

CHANG, CK ;

EBINA, F .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (15) :778-779

[5] PREPARATION AND CHARACTERIZATION OF SOME HYDROXY COMPLEXES OF IRON(III) PORPHYRINS [J].

CHENG, RJ ;

LATOSGRAZYNSKI, L ;

BALCH, AL .

INORGANIC CHEMISTRY, 1982, 21 (06) :2412-2418

[6] SOME PROPERTIES OF A SOLUBLE METHANE MONO-OXYGENASE FROM METHYLOCOCCUS-CAPSULATUS STRAIN BATH [J].

COLBY, J ;

DALTON, H .

BIOCHEMICAL JOURNAL, 1976, 157 (02) :495-497

[7]

COWAN JJ, COMMUNICATION

[8]

de Montellano P.R.O., 1986, CYTOCHROME P 450

[9] EFFECT OF FLUORINATION OF THE MESO-PHENYL GROUPS ON SELECTIVE TETRAPHENYLPORPHYRINATOMETAL(III)-CATALYSED REACTIONS OF ISOBUTANE WITH MOLECULAR-OXYGEN [J].

ELLIS, PE ;

LYONS, JE .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (17) :1189-1190

[10] EFFECT OF AXIAL AZIDE ON THE SELECTIVE, LOW-TEMPERATURE METALLOPORPHYRIN-CATALYZED REACTIONS OF ISOBUTANE WITH MOLECULAR-OXYGEN [J].

ELLIS, PE ;

LYONS, JE .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (16) :1187-1188

← 1 2 3 4 →