FREQUENCY DISPERSION ASSOCIATED WITH A NONHOMOGENEOUS INTERFACIAL CAPACITANCE

被引：13

作者：

KURTYKA, B

DELEVIE, R

机构：

[1] Department of Chemistry, Georgetown University, Washington

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1992年 / 322卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(92)80067-E

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The interfacial capacitance of the metal-solution interface, at a given applied potential, often depends strongly on the nature of the exposed crystal face. Consequently, capacitance measurements on a polycrystalline electrode may exhibit frequency dispersion. We describe a simple numerical method to demonstrate the existence of this effect.

引用

页码：63 / 77

页数：15

共 6 条

[1] AC CYCLIC VOLTAMMETRY - DIGITAL-SIMULATION STUDY OF SLOW SCAN LIMIT CONDITION FOR A REVERSIBLE ELECTRODE PROCESS [J].