2,2',3,3',5,5'-HEXAPHENYL-[1,1'-BIPHENYL]-4,4'-DIOLS AS MONOMER UNITS FOR REDOX POLYMERS - SYNTHESIS AND POLYMERIZATION STRATEGIES

被引：3

作者：

DECARVALHO, HN

KIM, WG

HAY, AS

机构：

[1] Department of Chemistry, McGill University, Montreal, P.Q., H3A 2K6

来源：

JOURNAL OF MACROMOLECULAR SCIENCE-PURE AND APPLIED CHEMISTRY | 1993年 / A30卷 / 6-7期

基金：

加拿大自然科学与工程研究理事会;

关键词：

D O I：

10.1080/10601329308009415

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

2,2',3,3',5,5'-Hexaphenyl-[1,1',-biphenyl]-4,4'-diol (Ib), which is prepared by the oxidative coupling of 2,3,6-triphenylphenol, and its oxidized form (IIIb) constitute a powerful oxidation-reduction system. The oxidative coupling reaction is carried out in the presence of molecular oxygen with copper(I) chloride as a catalyst and butyronitrile as ligand and solvent. An approach to the incorporation of such biphenols into an oxidation-reduction polymer is presented.

引用

页码：385 / 397

页数：13

共 13 条

[1] SYNTHESEN ISOTOP MARKIERTER 2.4.6-TRIPHENYL-PHENOLE [J].

DIMROTH, K ;

BERNDT, A ;

VOLLAND, R .

CHEMISCHE BERICHTE-RECUEIL, 1966, 99 (09) :3040-&

[2]

DIMROTH K, 1978, CHEM BER, P264

[3] POLY(2,6-DIARYL-1,4-PHENYLENE OXIDES) [J].

HAY, AS ;

CLARK, RF .

MACROMOLECULES, 1970, 3 (05) :533-&

[4] POLY(2,6-DIPHENYL-1,4-PHENYLENE OXIDE) [J].

HAY, AS .

MACROMOLECULES, 1969, 2 (01) :107-&

[5]

HAY AS, 1962, J POLYM SCI A2, V58, P581, DOI 10.1002/pol.1962.1205816634

[6]

HAY AS, 1965, TETRAHEDRON LETT, V47, P4241

[7] SYNTHESIS OF "POLY(P-HYDROXY-ALPHA-METHYLSTYRENE) BY CATIONIC POLYMERIZATION AND CHEMICAL MODIFICATION [J].

ITO, H ;

WILLSON, CG ;

FRECHET, JMJ ;

FARRALL, MJ ;

EICHLER, E .

MACROMOLECULES, 1983, 16 (04) :510-517

[8] SYNTHESIS OF SOLUBLE POLY(ARYLENE ETHER)S WITH HIGH GLASS-TRANSITION TEMPERATURES FROM HINDERED BIPHENOLS [J].

KIM, WG ;

HAY, AS .

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1992, 54-5 :331-336

[9]

MAIER G, 1963, ANGEW CHEM, P619

[10]

MANECKE G, 1972, PURE APPL CHEM C, P181

← 1 2 →