ABSOLUTE-CONFIGURATION AT C24 OF THE ECDYSTEROIDS DACRYSTERONE, PTEROSTERONE AND PONASTERONE-C

被引：13

作者：

BLUNT, JW ^{[1
]}

LANE, GA ^{[1
]}

MUNRO, MHG ^{[1
]}

RUSSELL, GB ^{[1
]}

机构：

[1] DSIR,DIV APPL BIOCHEM,PALMERSTON NORTH,NEW ZEALAND

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1979年 / 32卷 / 04期

关键词：

D O I：

10.1071/CH9790779

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The shielding values in 13C n.m.r. spectra of the ecdysteroids dacrysterone, pterosterone, and ponasterone C have been assigned, together with those for the 20, 22- and 22, 24-benzylidene acetal derivatives of the latter. From the n.m.r. data the C24 configuration of dacrysterone is assigned as 24R, while the 24S configuration is assigned to pterosterone and ponasterone C. © 1979, CSIRO. All rights reserved.

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页码：779 / 782

页数：4

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