3-IMINO-1,2-DIOXETANE VIA SINGLET OXYGENATION OF A KETENIMINE

被引:10
作者
ADAM, W [1 ]
DELUCCHI, O [1 ]
QUAST, H [1 ]
RECKTENWALD, R [1 ]
YANY, F [1 ]
机构
[1] UNIV WURZBURG,INST ORGAN CHEM,D-8700 WURZBURG,FED REP GER
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 10期
关键词
D O I
10.1002/anie.197907881
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In connection with “photochemistry without light” (or chemi‐energized electronic excitation) interest attaches to the 3‐imino‐1,2‐dioxetane 1, which has been synthesized as the first representative of its class. Compound 1, is stable at low tempertature. Homolysis of the OO bond to form the elusive 1,4‐dioxyl radical in heating could not be detected. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany
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页码:788 / 789
页数:2
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