STABILITY OF THE SILICON RUTHENIUM BOND IN THE PRESENCE OF A STRONG NUCLEOPHILE - PHASE-SENSITIVE H-1-NMR COSY AND CRYSTAL-STRUCTURE OF RU(CO)2(NH2CH2C6H5)2(SI(C6H5)(CH3)2)I

被引：8

作者：

RAPPOLI, BJ ^{[1
]}

MCGRATH, KJ ^{[1
]}

GEORGE, CF ^{[1
]}

COOPER, JC ^{[1
]}

机构：

[1] USN,RES LAB,STRUCT MATTER LAB,WASHINGTON,DC 20375

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 450卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80141-W

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ruthenium(II) complex RU(CO)2(NH2(NH2CH2C6H5)2(Si(C6H5)(CH3)2)I has been prepared by the reaction of RU(CO)4(Si(C6H5)(CH3)2)I with benzylamine. Two-dimensional homonuclear H-1 NMR experiments examine the scalar coupling of the enantiotopic amino and methylene protons of the benzylamine ligand. X-ray analysis of Ru(CO)2(NH2CH2-C6H5)2(Si(C6H5)(CH3)2)I.1/3C5H12 (triclinic; P1BAR; a=14.266(4), b=15.748(5), c=20.082(6) angstrom; alpha=94.38(3), beta=96.30(2), gamma=101.52(2)-degrees) indicates three crystallographically unique complexes form a clathrate with a pentane guest.

引用

页码：85 / 89

页数：5

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