BEHAVIOR OF ALUMINUM AS ANODE IN DIMETHYLSULFONE-BASED ELECTROLYTES

被引：45

作者：

LEGRAND, L

TRANCHANT, A

MESSINA, R

机构：

[1] Laboratoire d'Electrochimie Catalyse et Synthèse Organique, UMR 28, CNRS, 94320 Thiais

来源：

ELECTROCHIMICA ACTA | 1994年 / 39卷 / 10期

关键词：

ALUMINUM; DMSO(2) (DIMETHYLSULFONE); ALCL3 (ALUMINUM CHLORIDE); ANODE; ELECTRODEPOSITION;

D O I：

10.1016/0013-4686(94)85054-2

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Electrochemical behaviour of aluminium has been investigated in dimethylsulfone in presence of AlCl3 and LiCl salts in the temperature range of 80-160-degrees-C. Electrochemically active aluminium can be cathodically deposited and anodically stripped from LiAl2Cl7/DMSO2 electrolyte. High efficiencies (> 90%) have been obtained during cycling of aluminium in this medium. Comparison with other systems has been done.

引用

页码：1427 / 1431

页数：5

共 19 条

[1] AN AMBIENT-TEMPERATURE SECONDARY ALUMINUM ELECTRODE - ITS CYCLING RATES AND ITS CYCLING EFFICIENCIES [J].

AUBORN, JJ ;

BARBERIO, YL .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1985, 132 (03) :598-601

[2] COMPLEX BEHAVIOR OF AL DISSOLUTION IN NONAQUEOUS MEDIUM AS REVEALED BY IMPEDANCE SPECTROSCOPY [J].

BAI, L ;

CONWAY, BE .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (12) :3737-3747

[3]

BARD AJ, 1983, ELECTROCHIMIE PRINCI, P282

[4] SECONDARY ALUMINUM IRON (III) CHLORIDE BATTERIES WITH A LOW-TEMPERATURE MOLTEN-SALT ELECTROLYTE [J].

DONAHUE, FM ;

MANCINI, SE ;

SIMONSEN, L .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 1992, 22 (03) :230-234

[5] AN ALUMINUM ACID-BASE CONCENTRATION CELL USING ROOM-TEMPERATURE CHLOROALUMINATE IONIC LIQUIDS [J].

DYMEK, CJ ;

WILLIAMS, JL ;

GROEGER, DJ ;

AUBORN, JJ .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1984, 131 (12) :2887-2892

[6] INVESTIGATION OF SUBVALENT ION EFFECTS DURING ALUMINUM ANODIZATION IN MOLTEN NACL-AICL3 SOLVENTS [J].

GALE, RJ ;

OSTERYOU.RA .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1974, 121 (08) :983-987

[7] AN ALUMINUM CHLORINE RECHARGEABLE CELL EMPLOYING A ROOM-TEMPERATURE MOLTEN-SALT ELECTROLYTE [J].

GIFFORD, PR ;

PALMISANO, JB .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1988, 135 (03) :650-654

[8] A SUBSTITUTED IMIDAZOLIUM CHLOROALUMINATE MOLTEN-SALT POSSESSING AN INCREASED ELECTROCHEMICAL WINDOW [J].

GIFFORD, PR ;

PALMISANO, JB .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1987, 134 (03) :610-614

[9] A NOVEL INORGANIC LOW MELTING ELECTROLYTE FOR SECONDARY ALUMINUM-NICKEL SULFIDE BATTERIES [J].

HJULER, HA ;

VONWINBUSH, S ;

BERG, RW ;

BJERRUM, NJ .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (04) :901-906

[10] ALUMINUM ELECTRODE IN ALCL3-ALKALI-HALIDE MELTS [J].

HOLLECK, GL ;

GINER, J .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1972, 119 (09) :1161-&

← 1 2 →