ELECTRON SPECTROSCOPIC STUDY OF THE INTERACTION OF OXYGEN WITH CO(1120) AND OF COADSORPTION WITH WATER

被引：32

作者：

GRELLNER, F ^{[1
]}

KLINGENBERG, B ^{[1
]}

BORGMANN, D ^{[1
]}

WEDLER, G ^{[1
]}

机构：

[1] UNIV ERLANGEN NURNBERG, INST PHYS & THEORET CHEM, D-91058 ERLANGEN, GERMANY

来源：

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA | 1995年 / 71卷 / 02期

关键词：

AES; CO(11(2)OVER-BAR-0); OXYGEN; UPS; WORK FUNCTION; XPS;

D O I：

10.1016/0368-2048(94)02261-5

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Coverage dependence of oxygen adsorption on the hexagonal Co(11 ($) over bar 20) surface is studied at 100 and 320 K by means of Auger electron spectroscopy (AES), photoelectron spectroscopy (XPS, UPS) and change in work function (Delta phi). Adsorption of oxygen at 100 K leads to the formation of Co3O4-like features together with adsorbed oxygen. An influence of a precursor on the adsorption kinetics is proposed. Oxygen at 320 K builds up CoO, and the uptake behaviour is explained best in terms of chemisorption and oxide nucleation followed by island growth of the oxide. The explanation of the nature of a second oxygen species, observed in the Ols XP spectra, and the characterisation of OH are facilitated by a coadsorption experiment with oxygen and water at 100 K.

引用

页码：107 / 115

页数：9

共 38 条

[1] EELFS STUDY OF OXYGEN-CHEMISORPTION ON COBALT
ATREI, A
BARDI, U
ROVIDA, G
TORRINI, M
ZANAZZI, E
MAGLIETTA, M
[J]. SURFACE SCIENCE, 1987, 189 : 459 - 465
[2] OXIDATION OF CO(POLY) AND CO(1010) SURFACES - STRUCTURE AND TEMPERATURE EFFECTS
BOGEN, A
KUPPERS, J
[J]. SURFACE SCIENCE, 1983, 134 (01) : 223 - 236
[3] BRENNAN D, 1966, DISCUSS FARADAY SOC, P95
[4] OXYGEN-CHEMISORPTION, SURFACE OXIDATION, AND THE OXIDATION OF CARBON-MONOXIDE ON COBALT(0001)
BRIDGE, ME
LAMBERT, RM
[J]. SURFACE SCIENCE, 1979, 82 (02) : 413 - 424
[5] THE KINETICS AND MECHANISM OF THE INTERACTION OF OXYGEN WITH NI(100)
BRUNDLE, CR
HOPSTER, H
[J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1981, 18 (02): : 663 - 664
[6] X-RAY PHOTOEMISSION STUDY OF INTERACTION OF OXYGEN AND AIR WITH CLEAN COBALT SURFACES
BRUNDLE, CR
CHUANG, TJ
RICE, DW
[J]. SURFACE SCIENCE, 1976, 60 (02) : 286 - 300
[7] BRUNDLE CR, 1991, CHEM PHYSICS SOLID S, V3
[8] HYDROXYL-GROUPS ON OXIDE SURFACES - NIO(100), NIO(111) AND CR2O3(111)
CAPPUS, D
XU, C
EHRLICH, D
DILLMANN, B
VENTRICE, CA
ALSHAMERY, K
KUHLENBECK, H
FREUND, HJ
[J]. CHEMICAL PHYSICS, 1993, 177 (02) : 533 - 546
[9] OXYGEN INTERACTION WITH COSI(100) AND COSI2(100) SURFACES
CASTRO, G
HULSE, JE
KUPPERS, J
GONZALEZELIPE, AR
[J]. SURFACE SCIENCE, 1982, 117 (1-3) : 621 - 628
[10] INTERACTION OF OXYGEN WITH HCP (0001) RECRYSTALLIZED COBALT SURFACES
CASTRO, GR
KUPPERS, J
[J]. SURFACE SCIENCE, 1982, 123 (2-3) : 456 - 470

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