PREPARATION AND CRYSTAL-STRUCTURE OF TRANS-[NIBR(C6H3-2,6-(CH(2)PCY(2))(2))]

被引:47
作者
KENNEDY, AR
CROSS, RJ
MUIR, KW
机构
[1] Chemistry Department, University of Glasgow, Glasgow
关键词
CRYSTAL STRUCTURES; METALATION; NICKEL COMPLEXES; ORGANOMETALLIC COMPLEXES;
D O I
10.1016/0020-1693(94)04321-L
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis of trans-[NiBr{C6H3-2,6-(CH(2)PCy(2))(2)}], Cy = cyclohexyl, and its characterisation by spectroscopy and single crystal X-ray analysis are described. The constraints imposed by the bulky terdentate ligand lead only to minor distortions of the square planar nickel(II) coordination (P-Ni-P=161.6(1)degrees). The nickel coordination is compared with those found in related complexes with terdentate N- and P-donor ligands.
引用
收藏
页码:195 / 200
页数:6
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