APPLICATION OF THERMODYNAMIC PERTURBATION-THEORY TO MULTICENTER LENNARD-JONES MOLECULES - RESULTS FOR CF4, CCL4, NEO-C5H12 AND SF6 AS TETRAHEDRAL AND OCTAHEDRAL MODELS

被引：32

作者：

LUSTIG, R

机构：

[1] Ruhr-Univ Bochum, Bochum, West Ger, Ruhr-Univ Bochum, Bochum, West Ger

来源：

FLUID PHASE EQUILIBRIA | 1987年 / 32卷 / 02期

关键词：

CARBON TETRAFLUORIDE - HARD FUSED SPHERE BODIES - MULTICENTER LENNARD-JONES MOLECULES - SULFUR HEXAFLUORIDE - THERMODYNAMIC PERTURBATION THEORY;

D O I：

10.1016/0378-3812(87)85032-X

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Model fluids consisting of regular tetrahedral four- and five-center and regular octahedral six- and seven-center Lennard-Jones molecules are considered. The vapor-liquid equilibrium is determined by using perturbation theory on the liquid and virial expansion up to second virial coefficient on the gas side. Comparison is made with experimental data of CF//4, CCl//4, neo-C//5H//1//2 and SF//6.

引用

页码：117 / 137

页数：21

共 25 条

[1]

[Anonymous], 1980, VIRIAL COEFFICIENTS

[2] DESCRIPTION OF POLYATOMIC REAL SUBSTANCES BY TWO-CENTER LENNARD-JONES MODEL FLUIDS. [J].