MOSSBAUER SPECTROSCOPIC STUDIES OF CUBANE-TYPE CLUSTERS OF [MO3FES4(NH3)9(H2O)]CL4 AND [MO3FES4(H2O)10](PTS)4 7H2O (PTS - CH3(C6H4)SO3-

被引：8

作者：

KATADA, M ^{[1
]}

AKASHI, H ^{[1
]}

SHIBAHARA, T ^{[1
]}

SANO, H ^{[1
]}

机构：

[1] OKAYAMA UNIV SCI,DEPT CHEM,OKAYAMA 700,JAPAN

来源：

JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY-LETTERS | 1990年 / 145卷 / 02期

关键词：

D O I：

10.1007/BF02172365

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Mixed-metal cubane-type clusters of [Mo3FeS4(NH3)9(H2O)Cl4 and [Mo3FeS4(H2O)10](pts)4.7H2O have been characterized by means of57Fe-Mössbauer spectroscopy. The Mössbauer parameters indicate that the oxidation states of iron in the cluster compounds are ascribed to +2.54 and +2.39, respectively. © 1990 Akadémiai Kiadó.

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页码：143 / 149

页数：7

相关论文

共 17 条

[1] NOVEL CUBANE-TYPE MOLYBDENUM TIN CLUSTER COMPLEXES [(H2O)9MO3S4SNS4MO3(H2O)9]8+ AND MO3SNS4(AQ)6+ [J].

AKASHI, H ;

SHIBAHARA, T .

INORGANIC CHEMISTRY, 1989, 28 (15) :2906-2907

[2]

AKASHI H, 1988, 26 INT COORD CHEM C

[3] THE MO3S44+ AQUO ION [J].

COTTON, FA ;

DORI, Z ;

LLUSAR, R ;

SCHWOTZER, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (23) :6734-6735

[4]

FRANKEL RB, 1974, J PHYS-PARIS, V35, P107

[5] MOSSBAUER FE-57 ISOMER-SHIFT AS A MEASURE OF VALENCE IN MIXED-VALENCE IRON SULFIDES [J].

GOODENOUGH, JB ;

FATSEAS, GA .

JOURNAL OF SOLID STATE CHEMISTRY, 1982, 41 (01) :1-22

[6] EMPIRICAL BONDING RELATIONSHIPS IN METAL-IRON-SULFIDE COMPOUNDS [J].

HOGGINS, JT ;

STEINFINK, H .

INORGANIC CHEMISTRY, 1976, 15 (07) :1682-1685

[7] COMPLETE SYNTHESIS OF THE SERIES OF TRIANGULAR OXO SULFIDO BRIDGED MOLYBDENUM(IV) COMPLEXES AS AQUA IONS [J].

KATHIRGAMANATHAN, P ;

MARTINEZ, M ;

SYKES, AG .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (20) :1437-1439

[8] SYNTHETIC ANALOGS OF 4-FE ACTIVE-SITES OF REDUCED FERREDOXINS - ELECTRONIC PROPERTIES OF TETRANUCLEAR TRIANIONS [FE4S4(SR)4]3-, AND STRUCTURE OF [(C2H5)3(CH3)N]3[FE4S4(SC6H5)4] [J].

LASKOWSKI, EJ ;

FRANKEL, RB ;

GILLUM, WO ;

PAPAEFTHYMIOU, GC ;

RENAUD, J ;

IBERS, JA ;

HOLM, RH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (17) :5322-5337

[9] REACTION PATHS IN THE FORMATION OF TRIANGULAR AND CUBOIDAL MOLYBDENUM-SULFUR CLUSTER COMPLEXES AS AQUA IONS BY REDUCTION OF MOLYBDENUM(V) DIMERS [J].

MARTINEZ, M ;

OOI, BL ;

SYKES, AG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (15) :4615-4619

[10]

MENIL F, 1985, J PHYS CHEM SOLIDS, V46, P763, DOI 10.1016/0022-3697(85)90001-0