HIGHLY REGIOSELECTIVE RING-OPENING OF 2,3-EPOXY ALCOHOL METHANESULFONATES

被引：26

作者：

GAO, LX ^{[1
]}

SAITOH, H ^{[1
]}

FENG, F ^{[1
]}

MURAI, A ^{[1
]}

机构：

[1] HOKKAIDO UNIV, FAC SCI, DEPT CHEM, SAPPORO, HOKKAIDO 060, JAPAN

来源：

CHEMISTRY LETTERS | 1991年 / 10期

关键词：

D O I：

10.1246/cl.1991.1787

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of 2,3-epoxy-1-ol methanesulfonates with diethyl-aluminum chloride or with the mixture of diethylaluminum chloride and diethylamine hydrobromide in dichloromethane gave rise to regio-selectively the corresponding 3-chloro- and 3-bromo-1,2-diol 1-methanesulfonates, respectively, in excellent yields.

引用

页码：1787 / 1790

页数：4

共 9 条

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