A NEW REACTION TYPE IN THE CONVERSION OF ENAMINES WITH 1,4-DIPHENYL-2-BUTENE-1,4-DIONE TO GIVE CAGE COMPOUNDS

被引：13

作者：

KAUPP, G

POGODDA, U

ATFAH, A

MEIER, H

VIERENGEL, A

机构：

[1] YARMOUK UNIV,DEPT CHEM,IRBID,JORDAN

[2] UNIV MAINZ,INST ORGAN CHEM,W-6500 MAINZ,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 06期

关键词：

D O I：

10.1002/anie.199207681

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Spherical oxygenated heteropolycycles 3, containing stable acetal groups of a hitherto unknown type, can be obtained with surprising ease by the action of simple enamines 1 (n = 1-4) on the diketone 2. An ene addition is followed by a thermal [2 + 2 + 2]cycloaddition of the two carbonyl groups to the enamine double bond. Mor = morpholino.

引用

页码：768 / 770

页数：3

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