SYNTHESIS, CONDUCTIVITY, AND STRUCTURE OF A NOVEL ORGANIC CONDUCTOR (TMET-STF)2CLO4 - COEXISTENCE OF ONE-DIMENSIONAL AND 2-DIMENSIONAL DONOR COLUMNS

被引：23

作者：

OKANO, Y

SAWA, H

AONUMA, S

KATO, R

机构：

来源：

CHEMISTRY LETTERS | 1993年 / 11期

关键词：

D O I：

10.1246/cl.1993.1851

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An organic pi-donor TMET-STF (trimethylene(ethylenedithio)diselenadithiafulvalene) was synthesized using a method via a titanocene complex. The cation radical salt (TMET-STF)2ClO4 is metallic down to 22 K and shows an upturn of resistivity. Crystal structure analysis and band calculation indicate that this system contains two types of donor columns; the one is one-dimensional and the other is two-dimensional.

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页码：1851 / 1854

页数：4

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