SYNTHESIS, STRUCTURES AND REACTIONS OF NEW THERMALLY STABLE SILYLENES

被引：200

作者：

GEHRHUS, B

LAPPERT, MF

HEINICKE, J

BOESE, R

BLASER, D

机构：

[1] UNIV GREIFSWALD, INST ANORGAN CHEM, D-17487 GREIFSWALD, GERMANY

[2] UNIV ESSEN GESAMTHSCH, INST ANORGAN CHEM, D-45117 ESSEN, GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 19期

关键词：

D O I：

10.1039/c39950001931

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two representatives 1a and 1b of a new series of stable but reactive bis(amino)silylenes, derived from the N,N'-dineopentyl-1,2-phenylenediamido ligand RC(6)H(3)[($) over bar N(CH(2)Bu(t))](2), have been prepared by reductive elimination from RC(6)H(3)N(CH(2)Bu(t))]2SiCl2 and characterised by NMR spectroscopy and for 1a by X-ray crystallography; the silylenes Si[N(CH2BUt)]2C6H3-1,2-R (R = H 1a or 4-Me 1b) readily undergo oxidative addition with EtOH or Mel.

引用

页码：1931 / 1932

页数：2

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