ENANTIOSELECTIVE SYNTHESIS OF ALL 4 STEREOISOMERS OF (2E,4E)-4,6,10,12-TETRAMETHYL-2,4-TRIDECADIEN-7-ONE, THE SEX-PHEROMONE OF MATSUCOCCUS PINE BAST SCALE

被引：9

作者：

LIN, GQ

XU, WC

机构：

[1] Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, 200032

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 37期

关键词：

D O I：

10.1016/S0040-4039(00)73817-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A facile enantioselective synthesis of all four stereoisomers of (2E,4E)-4,6,10,12-tetramethyl-2,4-tridecadien-7-one 1, the primary sex pheromone of matsucoccus pine bast scale is described. The stereochemistry at C-6 and C-10 of 1 was constructed by using optically active citronellal as starting material and by the asymmetric Aldol reaction.

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页码：5931 / 5934

页数：4

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