CARBANION REACTIVITY - KINETICS OF THE REACTIONS OF BENZYL CYANIDE ANIONS WITH AROMATIC NITROCOMPOUNDS

被引：22

作者：

ATHERTON, JH

CRAMPTON, MR

DUFFIELD, GL

STEVENS, JA

机构：

[1] UNIV DURHAM,DEPT CHEM,DURHAM DH1 3LE,ENGLAND

[2] ZENECA FINE CHEM MFG ORG,HUDDERSFIELD HD2 1FF,W YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 1995年 / 03期

关键词：

D O I：

10.1039/p29950000443

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Rate and equilibrium measurements are reported for the reactions in methanol of carbanions derived from 12 ring-substituted benzyl cyanides with 1,3,5-trinitrobenzene to give sigma-adducts. Some data for reaction of the carbanions with 4-nitrobenzofuroxan were also measured. With increasing carbanion reactivity, rate constants approach a limit of just below 10(9) dm(3) mol(-1) s(-1). Intrinsic reactivities of carbanions in sigma-adduct forming transfer reactions are compared.

引用

页码：443 / 447

页数：5

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