KINETICS OF CHLORINE EVOLUTION - COMPARATIVE-STUDY

被引：46

作者：

TILAK, BV

机构：

[1] Hooker Chemical Corporation, Research Center, Grand Island

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1979年 / 126卷 / 08期

关键词：

chlorine evolution; stoichiometric number; Tafel slopes;

D O I：

10.1149/1.2129274

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Chlorine evolution kinetics were studied on Pt, Ir, Rh, Pt-Ir, Ru, RuO2 + TiO2 on Ti, C (vitreous), and Fe3O4 from 5M NaCl solutions (pH ~ 3.5) at 95° C. From the Tafel slopes and stoichiometric numbers, the nature of the slow step during chlorine evolution on most of these surfaces appears to be one involving recombination or electrochemical desorption of adsorbed intermediate species, based on this preliminary study. © 1979, The Electrochemical Society, Inc. All rights reserved.

引用

页码：1343 / 1348

页数：6

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