KINETICS OF THE REACTION IN CU-FE AND CU-CR MIXED OXIDES

被引:9
作者
ELBELLIHI, AA [1 ]
ABDELBADEI, AM [1 ]
DIEFALLAH, EHM [1 ]
机构
[1] FAC SCI BENHA,DEPT CHEM,BENHA,EGYPT
关键词
D O I
10.1016/0040-6031(90)80214-J
中图分类号
O414.1 [热力学];
学科分类号
摘要
The kinetics of the copper ferrite and copper chromite spinel formation reactions were followed in the temperature range 500-800 °C. Kinetic analysis of fractional reaction-time data showed that the reactions are best described by the two-dimensional (D2), Jander's (D3) and Ginstling-Brounshtein (D4) diffusion equations. The activation energies calculated according to these models were found to be model-independent and have the values 59.0 ±1.5 and 97.6 ±3.5 kJ mol-1 for the CuFe2O4 and CuCr2O4 formation reactions, respectively. © 1990.
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页码:147 / 152
页数:6
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