SYNTHESIS OF ORGANOPALLADIUM(IV) COMPLEXES BY HALOGEN EXCHANGE, AND THE STRUCTURE OF THE AZIDOPALLADIUM(II) COMPLEX FORMED ON REDUCTIVE ELIMINATION OF ETHANE FROM PD(N3)ME2(CH2PH)(BPY)

被引：10

作者：

CANTY, AJ ^{[1
]}

TRAILL, PR ^{[1
]}

SKELTON, BW ^{[1
]}

WHITE, AH ^{[1
]}

机构：

[1] UNIV WESTERN AUSTRALIA,DEPT PHYS & INORGAN CHEM,NEDLANDS,WA 6009,AUSTRALIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 402卷 / 02期

基金：

澳大利亚研究理事会;

关键词：

D O I：

10.1016/0022-328X(91)83076-G

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new route to organopalladium(IV) complexes is described, involving replacement of bromine in the 2,2'-bipyridyl complex PdBrMe2(CH2Ph)(bpy), by other halogen or pseudohalogen groups. H-1 NMR studies of the decomposition of PdXMe2(CH2Ph)(bpy) in warm (CD3)2CO indicate that a selectivity in reductive elimination of alkanes occurs, to give ethane (X = Br, N3, NCS), or a mixture of ethane and ethylbenzene in ca. 9/1 ratio (X = F, Cl, I). The reductive elimination product azido(2,2'-bipyridyl)benzylpalladium(II) has been characterized by X-ray crystallography.

引用

页码：C33 / C36

页数：4

共 19 条

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