1,2-DINITROSOBENZENE IN ARGON MATRICES AT 14-K

被引：39

作者：

DUNKIN, IR ^{[1
]}

LYNCH, MA ^{[1
]}

BOULTON, AJ ^{[1
]}

HENDERSON, N ^{[1
]}

机构：

[1] UNIV E ANGLIA,SCH CHEM SCI,NORWICH NR4 7TJ,NORFOLK,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 17期

关键词：

D O I：

10.1039/c39910001178

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photolysis of benzofurazan 1-oxide 3 and 2-nitrophenyl azide 7 in Ar matrices at 14 K yielded 1,2-dinitrosobenzene 4, which had not previously been characterized; the IR and UV absorptions of matrix-isolated 4 have been recorded, and its thermal and photochemical reversion to 3 has also been observed, N-15 labelling experiments lend strong support to the assignment.

引用

页码：1178 / 1179

页数：2

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