THE PREPARATION AND REACTIONS OF 1,6-DIPHOSPHATRICYCLO[4.4.4.0]TETRADECANEDIIUM DITRIFLUOROMETHANESULFONATE

被引：26

作者：

ALDER, RW

GANTER, C

HARRIS, CJ

ORPEN, AG

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 17期

关键词：

D O I：

10.1039/c39920001172

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

1,6-Diphosphatricyclo[4.4.4.0]tetradecanediium ditriflate, prepared by the reaction of 1,6-diphosphabicyclo[4.4.0]decane with 1,4-bis(trifluoromethanesulfonyloxy)butane, is stable in acidic aqueous solutions and reaction with nucleophiles (X = F-, MeO-, H-1) gives products with X-P-P+ bonding, hydroxide ion giving the diphosphine monoxide but even this retains partial P-P bonding: the hydride adduct reacts with Bu(n)Li to give 1,4-bis(phospholan-1-yl)butane rather than the expected 1,6-diphosphabicyclo[4.4.4]tetradecane.

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页码：1172 / 1174

页数：3

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