BUTATRIENES BY DESULFURIZATION OF CYCLIC TRITHIOCARBONATES

被引:11
作者
HERGES, R
HOOCK, C
机构
[1] Institut Für Organische Chemie, Universität Erlangen-Nürnberg, Erlangen, D-W-8520
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 12期
关键词
D O I
10.1002/anie.199216111
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel synthesis of cumulenes by addition of potassium trithiocarbonate to 1,4-difunctionalized 2-butynes 1 and subsequent desulfurization of the cyclic trithiocarbonate 2 affords substituted butatrienes 3 in good yields and under mild conditions.
引用
收藏
页码:1611 / 1613
页数:3
相关论文
共 25 条
[1]  
BRANDSMA L, 1988, PREPARATIVE ACETYLEN, P256
[2]   UBER DARSTELLUNG UND EIGENSCHAFTEN EINIGER CYCISCHER UND POLYMERER TRITHIOKOHLENSAUREESTER [J].
BRAUN, D ;
KIESSEL, M .
MONATSHEFTE FUR CHEMIE UND VERWANDTE TEILE ANDERER WISSENSCHAFTEN, 1965, 96 (02) :631-&
[3]   THE USE OF C-13 NMR-SPECTROSCOPY FOR THE CHARACTERIZATION OF CARBONATES, THIOCARBONATES, DITHIOCARBONATES AND TRITHIOCARBONATES [J].
COPELAND, C ;
CONWAY, RJ ;
PATRONI, JJ ;
STICK, RV .
AUSTRALIAN JOURNAL OF CHEMISTRY, 1981, 34 (03) :555-557
[4]   DESULFURIZATION REACTIONS WITH IRON CARBONYL-COMPOUNDS - CARBONYL(DIOXOLANYLIDENE)IRON COMPLEXES FROM THIONOCARBONATES [J].
DAUB, J ;
ENDRESS, G ;
ERHARDT, U ;
JOGUN, KH ;
KAPPLER, J ;
LAUMER, A ;
PFIZ, R ;
STEZOWSKI, JJ .
CHEMISCHE BERICHTE-RECUEIL, 1982, 115 (05) :1787-1809
[5]  
DAUB J, 1972, TETRAHEDRON LETT, P4435
[6]   REACTION PLANNING - COMPUTER-AIDED DISCOVERY OF A NOVEL ELIMINATION-REACTION [J].
HERGES, R ;
HOOCK, C .
SCIENCE, 1992, 255 (5045) :711-713
[7]  
HERGES R, 1991, SYNTHESIS-STUTTGART, P1151
[8]  
HOPF H, 1980, CHEM KETENES ALLEN 2, P863
[9]   TITANIUM-INDUCED REDUCTIVE ELIMINATION OF 2-YNE-1,4-DIOLS [J].
HUANG, JL ;
GOEDKEN, V ;
WALBORSKY, HM .
JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (17) :4128-4131
[10]   NOVEL SYNTHESIS OF BUTATRIENE DERIVATIVES BY REACTIONS OF 3-BROMO-3-ALKEN-1-YNES WITH ORGANOCOPPER(I) SPECIES [J].
KLEIJN, H ;
TIGCHELAAR, M ;
BULLEE, RJ ;
ELSEVIER, CJ ;
MEIJER, J ;
VERMEER, P .
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 240 (03) :329-333