SYNTHESIS OF DIENOIC ACIDS AND ESTERS BY CATIONIC PALLADIUM COMPLEX-CATALYZED CARBONYLATION OF ALKYNOLS AND ALKYNEDIOLS

被引：29

作者：

HUH, KT ^{[1
]}

ORITA, A ^{[1
]}

ALPER, H ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,10 MARIE CURIE,OTTAWA K1N 6N5,ONTARIO,CANADA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1993年 / 58卷 / 25期

关键词：

D O I：

10.1021/jo00077a008

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The cationic palladium(II) aquo hydride, trans-(Cy3P)2Pd(H)(H2O)+BF4-, is an excellent catalyst for the carbonylation of alkynols to dienoic acids and esters and of alkynediols to cross-conjugated diesters.

引用

页码：6956 / 6957

页数：2

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