SYNTHESIS OF DIENOIC ACIDS AND ESTERS BY CATIONIC PALLADIUM COMPLEX-CATALYZED CARBONYLATION OF ALKYNOLS AND ALKYNEDIOLS

被引:29
作者
HUH, KT [1 ]
ORITA, A [1 ]
ALPER, H [1 ]
机构
[1] UNIV OTTAWA,DEPT CHEM,10 MARIE CURIE,OTTAWA K1N 6N5,ONTARIO,CANADA
关键词
D O I
10.1021/jo00077a008
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The cationic palladium(II) aquo hydride, trans-(Cy3P)2Pd(H)(H2O)+BF4-, is an excellent catalyst for the carbonylation of alkynols to dienoic acids and esters and of alkynediols to cross-conjugated diesters.
引用
收藏
页码:6956 / 6957
页数:2
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