REMARKS ON THE ASSIGNMENTS OF TEMPERATURE-PROGRAMMED DESORPTION PEAKS FOR THE SURFACE SPECIES FORMED ON CU/ZNO AND ZNO IN THE METHANOL SYNTHESIS FROM CO

被引：10

作者：

FUJITA, S

ITO, H

TAKEZAWA, N

机构：

[1] Division of Materials Science and Engineering, Faculty of Engineering, Hokkaido University, Sapporo

来源：

CATALYSIS LETTERS | 1995年 / 33卷 / 1-2期

关键词：

CU/ZNO CATALYST; ZNO CATALYST; METHANOL SYNTHESIS; SURFACE FORMATE SPECIES; METHOXIDE SPECIES;

D O I：

10.1007/BF00817047

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Temperature programmed desorption (TPD), IR spectroscopy and chemical trapping of the surface species with H2O revealed that the TPD peak of CO frequently assigned to zinc formate species, which were formed in the course of the methanol synthesis from CO-H-2, arose from zinc methoxide species.

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页码：67 / 74

页数：8

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