POLARIZED FLUORESCENCE FROM PHOTO-DISSOCIATION FRAGMENTS - STUDY OF ICN PHOTOLYSIS USING SYNCHROTRON RADIATION

被引:26
作者
POLIAKOFF, ED
SOUTHWORTH, SH
SHIRLEY, DA
JACKSON, KH
ZARE, RN
机构
[1] UNIV CALIF BERKELEY LAWRENCE BERKELEY LAB,DEPT CHEM,BERKELEY,CA 94720
[2] UNIV CALIF BERKELEY LAWRENCE BERKELEY LAB,DIV MAT & MOLEC RES,BERKELEY,CA 94720
[3] STANFORD UNIV,DEPT CHEM,STANFORD,CA 94305
基金
美国国家科学基金会;
关键词
D O I
10.1016/0009-2614(79)80259-6
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Linearly polarized synchrotron radiation (1100-1700 A) is used to photodissociated ICN, and emission from the CN (B 2Σ+) fragment is analyzed for its degree of polarization, which is found to vary between 0 and 8%. This measurement establishes the direction of the absorption transition dipole moment in the molecular frame. © 1979.
引用
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页码:407 / 409
页数:3
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