REINVESTIGATION OF SYNTHETIC METHODS FOR ZINC MESO-TETRAPHENYLTETRABENZOPORPHYRIN

被引：33

作者：

ICHIMURA, K

SAKURAGI, M

MORII, H

YASUIKE, M

FUKUI, M

OHNO, O

机构：

[1] TOYO INK MFG CO LTD,TSUKUBA RES LAB,27 WADAI,TSUKUBA,IBARAKI 30042,JAPAN

[2] TOKYO INST TECHNOL,FAC SCI,DEPT CHEM,MEGURO KU,TOKYO 152,JAPAN

[3] RES INST POLYMERS & TEXT,TSUKUBA,IBARAKI 305,JAPAN

来源：

INORGANICA CHIMICA ACTA | 1990年 / 176卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)85087-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of 3-benzylidenephthalimidine (3-BPI) with zinc acetate for the preparation of the meso- tetraphenyltetrabenzoporphyrin zinc complex (ZnP4TBP) is reinvestigated. From the structural analyses of the reaction product with ultraviolet-visible absorption spectra, field desorption mass spectra (FDMS) and 1H NMR spectra, it is shown that this reaction procedure gives a complicated mixture of ZnTBP derivatives with meso-phenyl substituent(s) the number of which is from one to four. The product obtained by the reaction of isoindole with benzaldehyde in the presence of zinc acetate is also discussed. © 1990.

引用

页码：31 / 33

页数：3

共 14 条

[1] PHOTON-GATED SPECTRAL HOLE BURNING BY DONOR-ACCEPTOR ELECTRON-TRANSFER [J].