PHOTORESPONSIVE COORDINATION OF STILBAZOLES TO METALLOPORPHYRINS

被引：28

作者：

ISEKI, Y ^{[1
]}

WATANABE, E ^{[1
]}

MORI, A ^{[1
]}

INOUE, S ^{[1
]}

机构：

[1] UNIV TOKYO,DEPT SYNTHET CHEM,BUNKYO KU,TOKYO 113,JAPAN

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1993年 / 115卷 / 16期

关键词：

D O I：

10.1021/ja00069a033

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coordination of stilbazole derivatives to metalloporphyrins was investigated. Among the stilbazoles examined, a stilbazole with a bulky group such as 4-phenyl-3-stilbazole (4) showed considerable difference between the trans and cis isomers in its ability to coordinate to aluminum and zinc porphyrins with bulky peripheral substituents. The extent of coordination of 4 to metalloporphyrins could be changed by the trans --> cis isomerization of 4 upon UV irradiation.

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页码：7313 / 7317

页数：5

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