INTERRELATIONSHIP OF STRUCTURAL ELEMENTS ON TIO2(100)-(1X3)

被引：79

作者：

MURRAY, PW ^{[1
]}

LEIBSLE, FM ^{[1
]}

MURYN, CA ^{[1
]}

FISHER, HJ ^{[1
]}

FLIPSE, CFJ ^{[1
]}

THORNTON, G ^{[1
]}

机构：

[1] UNIV MANCHESTER,DEPT CHEM,MANCHESTER M13 9PL,LANCS,ENGLAND

来源：

PHYSICAL REVIEW LETTERS | 1994年 / 72卷 / 05期

关键词：

D O I：

10.1103/PhysRevLett.72.689

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

Scanning tunneling microscopy (STM) has been used to investigate the interaction of nanoscale structural elements associated with rutile TiO2(100)-(1 x 3). These are the 1 x 3 reconstruction, vicinal off-cut steps in the [001] direction, and up-down steps in the [010] direction. The STM data image the microfacet morphology of the 1 x 3 reconstruction suggested by diffraction measurements. They also provide an explanation for the stabilization of the up-down steps by the vicinal off-cut, which involves maximizing the area of the (110) microfacets at the expense of high-energy (001) step edges.

引用

页码：689 / 692

页数：4

共 14 条

[1] A SCANNING TUNNELING MICROSCOPY STUDY OF TIO2(100) SURFACE RECONSTRUCTIONS
CLARK, GW
KESMODEL, LL
[J]. ULTRAMICROSCOPY, 1992, 41 (1-3) : 77 - 81
[2] SCANNING-TUNNELING-MICROSCOPE STUDY OF ANTIPHASE DOMAIN BOUNDARIES, DISLOCATIONS, AND LOCAL MASS-TRANSPORT ON AU(110) SURFACES
GIMZEWSKI, JK
BERNDT, R
SCHLITTLER, RR
[J]. PHYSICAL REVIEW B, 1992, 45 (12): : 6844 - 6857
[3] OXYGEN-VACANCY SITES ON TIO2(100)1X3 USING SURFACE CORE-LEVEL-SHIFT PHOTOELECTRON DIFFRACTION
HARDMAN, PJ
PRAKASH, NS
MURYN, CA
RAIKAR, GN
THOMAS, AG
PRIME, AF
THORNTON, G
BLAKE, RJ
[J]. PHYSICAL REVIEW B, 1993, 47 (23): : 16056 - 16059
[4] HENRICH VE, 1993, SURFACE SCI OXIDE MA
[5] Murray P, UNPUB
[6] OBSERVATION OF ORDERED OXYGEN VACANCIES ON TIO2(100)1X3 USING SCANNING TUNNELING MICROSCOPY AND SPECTROSCOPY
MURRAY, PW
LEIBSLE, FM
FISHER, HJ
FLIPSE, CFJ
MURYN, CA
THORNTON, G
[J]. PHYSICAL REVIEW B, 1992, 46 (19): : 12877 - 12879
[7] STEP AND POINT-DEFECT EFFECTS ON TIO2 (100) REACTIVITY
MURYN, CA
HARDMAN, PJ
CROUCH, JJ
RAIKER, GN
THORNTON, G
LAW, DSL
[J]. SURFACE SCIENCE, 1991, 251 : 747 - 752
[8] IDENTIFICATION OF THE FACET PLANES OF PHASE-I TIO2(001) RUTILE BY SCANNING TUNNELING MICROSCOPY AND LOW-ENERGY ELECTRON-DIFFRACTION
POIRIER, GE
HANCE, BK
WHITE, JM
[J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY B, 1992, 10 (01): : 6 - 15
[9] STRUCTURE OF THE REDUCED TIO2(110) SURFACE DETERMINED BY SCANNING TUNNELING MICROSCOPY
ROHRER, GS
HENRICH, VE
BONNELL, DA
[J]. SCIENCE, 1990, 250 (4985) : 1239 - 1241
[10] A SCANNING TUNNELING MICROSCOPY AND SPECTROSCOPY STUDY OF THE TIO(2-X)(110) SURFACE
ROHRER, GS
HENRICH, VE
BONNELL, DA
[J]. SURFACE SCIENCE, 1992, 278 (1-2) : 146 - 156

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