NOVEL ALKYNYL-SUBSTITUTED (P-PHENYLENE)BISIODONIUM DITRIFLATES - PREPARATION AND REACTION WITH THIOCYANATE ION

被引：14

作者：

KITAMURA, T

FURUKI, R

ZHENG, L

FUJIMOTO, T

TANIGUCHI, H

机构：

来源：

CHEMISTRY LETTERS | 1992年 / 11期

关键词：

D O I：

10.1246/cl.1992.2241

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Novel alkynyl(p-phenylene)bisiodonium ditriflates were prepared in good to high yields by reaction of trimethylsilylalkynes with PhIO activated with 2 equivalents of triflic acid. Reaction of the alkynylbisiodonium salts with potassium thiocyanate gave alkynyl thiocyanates in high yields and suggested that the alkynylbisiodonium salts serve as an agent for alkynylation of a nucleophilic substrate.

引用

页码：2241 / 2244

页数：4

共 16 条

[1] [Anonymous], REV HETEROATOM CHEM
[2] [Anonymous], CHEM HALIDES PSEUDOH
[3] FISCHER DR, 1992, SYNLETT, P535
[4] KITAMURA T, 1991, MENDELEEV COMMUN, P148
[5] MERKUSHEV EB, 1987, RUSS CHEM REV, V56, P826
[6] MORIARTY RM, 1990, SYNLETT, P365
[7] HYPERVALENT IODINE IN ORGANIC-SYNTHESIS
MORIARTY, RM
PRAKASH, O
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1986, 19 (08) : 244 - 250
[8] MORIARTY RM, 1990, SYNTHESIS-STUTTGART, P431
[9] HYPERVALENT ORGANOIODINE COMPOUNDS IN ORGANIC-SYNTHESIS - REACTION WITH ORGANOSILICON AND TIN
OCHIAI, M
NAGAO, Y
[J]. JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1986, 44 (07) : 660 - 673
[10] ALKYNYLARYLIODONIUM TOSYLATES AND ARYL[BETA-(TOSYLOXY)VINYL]IODONIUM TOSYLATES FROM REACTIONS OF TERMINAL ALKYNES WITH [HYDROXY(TOSYLOXY)IODO]BENZENE
REBROVIC, L
KOSER, GF
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1984, 49 (24) : 4700 - 4702

← 1 2 →