VAPOR-LIQUID-EQUILIBRIUM DATA AT 298.15-K FOR BINARY-SYSTEMS CONTAINING METHYL ACETATE OR METHANOL WITH 2-METHOXYETHANOL OR 2-ETHOXYETHANOL

被引：22

作者：

MARTIN, MC

COCERO, MJ

MATO, RB

机构：

[1] UNIV VALLADOLID,ETSII,DEPT INGN ENERGET & FLUIDOMECAN,E-47011 VALLADOLID,SPAIN

[2] UNIV VALLADOLID,FAC CIENCIAS,DEPT INGN QUIM,E-47011 VALLADOLID,SPAIN

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1994年 / 39卷 / 03期

关键词：

D O I：

10.1021/je00015a030

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Isothermal vapor-liquid equilibria were measured at 298.15 K for the systems containing methyl acetate or methanol with 2-methoxyethanol or 2-ethoxyethanol. Mixtures containing methanol show a behavior close to ideal, while those containing methyl acetate exhibit positive deviations from ideality and satisfy the Redlich-Kister thermodynamic consistency test. The liquid-phase activity coefficients were fitted by using the van Laar, Wilson, NRTL, and NRTL-m (a modified NRTL equation) equations.

引用

页码：535 / 537

页数：3

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