NEAR-INFRARED DIODE-LASER ABSORPTION-SPECTROSCOPY OF THE (2,0) BAND OF THE ALPHA-2-PI-U-CHI-2-SIGMA-G+ SYSTEM OF THE N-2+ ION GENERATED IN A SUPERSONIC JET EXPANSION

被引:15
作者
HARADA, K
TANAKA, T
机构
[1] Department of Chemistry, Faculty of Science, Kyushu University 33, Higashiku, Fukuoka, 812, Hakozaki
关键词
D O I
10.1016/0009-2614(94)00880-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The A 2PI(u)-X 2SIGMA(g)+ band of the nitrogen molecular ion rotatinally cooled to typically 50 K in a pulsed supersonic jet expansion has been observed by direct absorption spectroscopy with near-infrared diode laser source. Rotational lines belonging to the (2, 0) vibrational band were observed with the signal-to-noise ratio greater than 40 by the use of the discharge modulation technique combined with dual-gated integration.
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页码:651 / 655
页数:5
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