ISOLATED SO4(2-) AND PO4(3-) ANIONS DO NOT EXIST

被引：132

作者：

BOLDYREV, AI ^{[1
]}

SIMONS, J ^{[1
]}

机构：

[1] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 09期

关键词：

D O I：

10.1021/j100060a015

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ab initio theoretical methods that incorporate effects of orbital relaxation and electron correlation are used to examine the possibility that doubly or triply charged oxy anions of the class SO42-, SeO42-, TeO42-, or PO43-, AsO43-, SbO43- are stable relative to electron detachment in the absence of any surrounding medium. In all of these cases, our findings indicate quite clearly that these multiply charged oxy anions are not stable.

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页码：2298 / 2300

页数：3

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