TRIFLUOROACETYLTRIPHENYLSILANE AS A POTENTIALLY USEFUL FLUORINE-CONTAINING BUILDING BLOCK - PREPARATION AND ITS TRANSFORMATION INTO 2,2-DIFLUORO ENOL SILYL ETHERS

被引：72

作者：

JIN, FQ ^{[1
]}

JIANG, BA ^{[1
]}

XU, YY ^{[1
]}

机构：

[1] ACAD SINICA,SHANGHAI INST ORGAN CHEM,ORGANOMETALL CHEM LAB,345 LINGLING LU,SHANGHAI 200032,PEOPLES R CHINA

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 09期

关键词：

D O I：

10.1016/S0040-4039(00)91901-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first example of perfluoroacylsilanes-trifluoroacetyltriphenylsilane was prepared in good yield and it has been converted into a series of 2,2-difluoro enol silyl ethers in almost quantitative yields by treatment with various organolithiums.

引用

页码：1221 / 1224

页数：4

共 11 条

[1] TRIPHENYLSILYL PHENYL KETONE [J].

BROOK, AG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (16) :4373-4375

[2] SOME MOLECULAR-REARRANGEMENTS OF ORGANOSILICON COMPOUNDS [J].

BROOK, AG .

ACCOUNTS OF CHEMICAL RESEARCH, 1974, 7 (03) :77-84

[3] NEW SYNTHESIS OF ACYLSILANES [J].

DUFFAUT, N ;

DUNOGUES, J ;

BIRAN, C ;

CALAS, R ;

GERVAL, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 161 (02) :C23-C24

[4]

Filler R., 1982, BIOMEDICAL ASPECTS F

[5] RECENT TRENDS IN THE SYNTHESIS OF ORGANOFLUORINE COMPOUNDS [J].

FUCHIKAMI, T .

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1984, 42 (09) :775-785

[6]

Hudlicky M., 1976, CHEM ORGANIC FLUORIN

[7] SYNTHESIS OF FLUORINE-CONTAINING MEDICINES [J].

KUMADAKI, I .

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1984, 42 (09) :786-793

[8]

RICCI A, 1989, SYNTHESIS-STUTTGART, P647

[9] SYNTHESIS AND APPLICATION OF FLUORINE-CONTAINING HETEROCYCLES [J].

TANAKA, K .

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 1990, 48 (01) :16-28

[10]

WELSH JT, 1987, TETRAHEDRON, V43, P3123

← 1 2 →