A NEW THIONATION REAGENT - PREPARATION OF PRIMARY THIOAMIDES FROM NITRILES

被引：22

作者：

BRILLON, D

机构：

[1] Institut Armand-Frappier, Université du Québec, Quebec H7N 4Z3, 531 Boul. Des Prairies, Laval, P.

来源：

SYNTHETIC COMMUNICATIONS | 1992年 / 22卷 / 10期

关键词：

D O I：

10.1080/00397919208021604

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Phosphorus decasulfide reacts with sodium sulfide (1:1 ratio) in tetrahydrofuran at 25-degrees-C to afford an in situ reagent 1C (5 eq.) that rapidly converts nitriles into thioamides at 20-degrees-C.

引用

页码：1397 / 1401

页数：5

共 8 条

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[3]

BRILLON D, IN PRESS SULFUR REPO

[4]

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[5]

SCHEEREN JW, 1973, SYNTHESIS-STUTTGART, P149

[6] STUDIES ON ORGANOPHOSPHORUS COMPOUNDS .55. THE TRANSFORMATION OF NITRILES TO THIOAMIDES WITH O,O-DIALKYLDITHIOPHOSPHORIC ACID [J].

SHABANA, R ;

MEYER, HJ ;

LAWESSON, SO .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1985, 25 (03) :297-305

[7]

SHALABI SE, 1970, VYSOKOMOL SOEDIN S B, V12, P421

[8] A NEW SYNTHESIS OF ALIPHATIC AND AROMATIC THIOAMIDES FROM NITRILES [J].

TAYLOR, EC ;

ZOLTEWICZ, JA .

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