(S)-2H-2-OXO-5,5-DIMETHYL-4(R)-PHENYL-1,3,2-DIOXAPHOSPHORINANE, A NEW REAGENT FOR THE ENANTIOMERIC EXCESS DETERMINATION OF UNPROTECTED AMINO-ACIDS USING P-31 NMR

被引：35

作者：

HULST, R

ZIJLSTRA, RWJ

DEVRIES, NK

FERINGA, BL

机构：

[1] UNIV GRONINGEN,GRONINGEN CTR CATALYSIS & SYNTH,DEPT ORGAN & MOLEC INORGAN CHEM,9747 AG GRONINGEN,NETHERLANDS

[2] DSM RES BV,ANALYT SECT,BASE CHEM & HYDROCARBONS,6160 MD GELEEN,NETHERLANDS

来源：

TETRAHEDRON-ASYMMETRY | 1994年 / 5卷 / 09期

关键词：

D O I：

10.1016/0957-4166(94)80081-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Diastereomeric amide derivatives of title phosphorinane 2 and unprotected amino acids are easily prepared in aqueous solutions, showing well separated signals in the P-31 NMR spectra allowing accurate e.e. determination.

引用

页码：1701 / 1710

页数：10

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