SYNTHESIS OF HYDROXY-TERMINATED POLY(VINYL ETHERS) BY LIVING CATIONIC POLYMERIZATION .2. POLY(2-CHLOROETHYL VINYL ETHER) - A TELECHELIC POLYMER WITH REACTIVE PENDANTS

被引：8

作者：

HASHIMOTO, T

AIZAWA, H

KODAIRA, T

机构：

[1] Department of Materials Science and Engineering, Faculty of Engineering, Fukui University, Fukui, 910, Bunkyo

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1995年 / 16卷 / 07期

关键词：

D O I：

10.1002/marc.1995.030160710

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Hydroxy-terminated telechelic poly(2-chloroethyl vinyl ether) (poly(CEVE)) was synthesized by water-based end-capping reaction of living poly(CEVE) with the initiating system CH3CHCl-OCH2CH2-OCOCH3/ZnCl2 in CH2Cl2 at -40 degrees C and subsequent end-group transformation of the acetate (alpha-end) and aldehyde (omega-end) groups into hydroxy groups. The obtained polymers possess controlled molecular weights and narrow molecular weight distributions.

引用

页码：521 / 526

页数：6

共 5 条

[1]

HASHIMOTO T, 1993, MAKROMOL CHEM, V194, P2323

[2] LIVING CATIONIC POLYMERIZATION OF 2-CHLOROETHYL VINYL ETHER - KINETICS, MECHANISM AND APPLICATION TO POLYMER SYNTHESIS [J].

HEROGUEZ, V ;

DEFFIEUX, A ;

FONTANILLE, M .

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA, 1990, 32 :199-216

[3] SYNTHESIS AND CHARACTERIZATION OF POLY(VINYLETHER)S WITH PENDANT MESOGENIC GROUPS [J].

HEROGUEZ, V ;

SCHAPPACHER, M ;

PAPON, E ;

DEFFIEUX, A .

POLYMER BULLETIN, 1991, 25 (03) :307-314

[4] SUBSTITUTION AND ELIMINATION-REACTIONS OF POLY(EPICHLOROHYDRIN) AND POLY(2-CHLOROETHYL VINYL ETHER) USING PHASE-TRANSFER CATALYSIS [J].

IIZAWA, T ;

NISHIKUBO, T ;

ICHIKAWA, M ;

SUGAWARA, Y ;

OKAWARA, M .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1985, 23 (07) :1893-1906

[5] SELECTIVE REDUCTIONS .28. THE FAST REACTION OF LITHIUM ALUMINUM-HYDRIDE WITH ALKYL-HALIDES IN TETRAHYDROFURAN - A REAPPRAISAL OF THE SCOPE OF THE REACTION [J].

KRISHNAMURTHY, S ;

BROWN, HC .

JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (02) :276-280

← 1 →