TRAPPING OF RADICAL INTERMEDIATES IN PHOTOREDUCTION OF BENZOPHENONE

被引：102

作者：

LEAVER, IH

RAMSAY, GC

机构：

[1] Division of Protein Chemistry, CSIRO

来源：

TETRAHEDRON | 1969年 / 25卷 / 23期

关键词：

D O I：

10.1016/S0040-4020(01)83073-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Radical intermediates formed during the photoreduction of benzophenone by alcohols, amines, phenols, sulphides, thiols, ethers, hydrocarbons and amides have been trapped by t-nitrosobutane and the resulting nitroxide radicals characterized in situ by ESR. In the case of 2,6-di-t-butylphenols and aliphatic sulphides evidence was obtained for radicals other than those expected. © 1969.

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页码：5669 / &

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